How to draw an electron flow arrow

1. Select the arrow type (single electron flow or electron pair flow). (Menu: Insert > Electron Flow)

2. Move the cursor over a bond, electron, or lone pair (or over the atom itself if the valence electrons are not displayed around it) of the structure on the canvas, and push the mouse button. (It will be the source of the electron flow.)

3. Select the destination: drag the arrow while holding down the mouse button and release the button over the destination to finalize the electron flow arrow.

Handling endpoints

Logic of the selection of electron flow arrow endpoints are the following:

If the source is an electron, or lone pair (or an atom), the destination can be:

• any atom;

• a bond connected to this atom;

• an incipient bond between this atom and any other atom.

If the source is a bond, the destination can be:

• an atom;

• a bond connected to this bond (has common ending atom);

• an incipient bond between an atom belonging to this bond and any other atom.

If one endpoint of the electron flow arrow is in an S-group and the other is not, the arrow has to connect to the attachment point of S-group.

Displaying electron flow arrows

Although an electron flow arrow can start from any atom or bond, its illustration in MarvinSketch follows certain rules:

If the source is an atom, the origin of a single electron flow arrow can be:

• a radical;

• an electron of a lone pair;

• the atom label if neither radicals nor lone pairs are displayed on the atom.

If the atom has more than one radical and/or lone pair, the user is free to decide from which electron to start the single electron flow arrow.

If the source is an atom, the origin of the electron pair flow arrow can be:

• a lone pair;

• the charge if lone pairs are not displayed;

• the atom label if the atom does not have any charge and lone pairs are not displayed.

If the atom has more than one lone pair, the user is free to decide from which lone pair to start the electron pair flow arrow.

If several electron flow arrows start from the same atom, MarvinSketch ensures that their arrangement is chemically correct:

• no more than one single electron flow arrow can start from a radical;

• no more than two single electron flow arrows can start from a lone pair;

• no more than one electron pair flow arrow can start from a lone pair.

If the source is a bond, the origin of the electron flow arrow is the midpoint of the bond.

In every case, the destination of an electron flow arrow is:

• an atom label if the destination is an atom;

• the midpoint of a bond if the destination is a bond;

• the midpoint (single electron flow) or the 3/4 point (electron pair flow) of the distance between two atoms if the destination is an incipient bond.